How can a microscopic filter seperate molecules by shape?

Kerry Q2008-01-17T11:53:03Z

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Because molecules have a particular shape. For example:

Octane has 8 carbons and 18 hydrogens, Methane has 1 carbon and 4 hydrogens.

Which is bigger?
A semipermiable membrane can distinguish between the two if it has picometer sized holes that only methane can fit through. Do you think Octane can fit through that same hole?