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Use the information below to calculate?

Delta H_2: CH4 (g)+2 O2 (g)--> CO2 (g)+2 H2O (g); delta H= -890kj CH4 (g) +O2 (g)--> CH2O (g)+ H2O (g); Delta H2=? CH2O (g)---> CO2 (g)+H2O (g); delta H3=-518kj

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  • ?
    Lv 6
    4 years ago
    Favorite Answer

    Reaction (1) :-

    CH₄(g) + 2O₂(g) -----> CO₂(g) + 2H₂O(g) ΔH = -890kJ

    ΔH = (ΔHp - ΔHr)

    -890kJ = (ΔHf_CO₂ + 2ΔHf_H₂O) - (ΔHf_CH₄ + 2ΔHf_O₂)

    ΔHf_O₂(g) = 0

    -890kJ = ΔHf_CO₂ + 2ΔHf_H₂O - ΔHf_CH₄ --------(1)

    Reaction (3) :-

    CH₂O(g) ------> CO₂(g) + H₂O(g) ΔH₃ = -518kJ

    -518kJ = ΔHf_CO₂ + ΔHf_H₂O - ΔHf_CH₂O

    518kJ = ΔHf_CH₂O - ΔHf_H₂O - ΔHf_CO₂ ------(2)

    Reaction (2) :-

    CH₄(g) + O₂(g) -----> CH₂O(g) + H₂O(g)

    ΔH₂ = ΔHf_CH₂O + ΔHf_H₂O - ΔHf_CH₄ ------(3)

    Sum of equations (1) and (2) gives equation (3)

    So ΔH₂ = (518kJ) + (-890kJ) = -372kJ

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