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Delta H_2: CH4 (g)+2 O2 (g)--> CO2 (g)+2 H2O (g); delta H= -890kj CH4 (g) +O2 (g)--> CH2O (g)+ H2O (g); Delta H2=? CH2O (g)---> CO2 (g)+H2O (g); delta H3=-518kj
1 Answer
- ?Lv 64 years agoFavorite Answer
Reaction (1) :-
CH₄(g) + 2O₂(g) -----> CO₂(g) + 2H₂O(g) ΔH = -890kJ
ΔH = (ΔHp - ΔHr)
-890kJ = (ΔHf_CO₂ + 2ΔHf_H₂O) - (ΔHf_CH₄ + 2ΔHf_O₂)
ΔHf_O₂(g) = 0
-890kJ = ΔHf_CO₂ + 2ΔHf_H₂O - ΔHf_CH₄ --------(1)
Reaction (3) :-
CH₂O(g) ------> CO₂(g) + H₂O(g) ΔH₃ = -518kJ
-518kJ = ΔHf_CO₂ + ΔHf_H₂O - ΔHf_CH₂O
518kJ = ΔHf_CH₂O - ΔHf_H₂O - ΔHf_CO₂ ------(2)
Reaction (2) :-
CH₄(g) + O₂(g) -----> CH₂O(g) + H₂O(g)
ΔH₂ = ΔHf_CH₂O + ΔHf_H₂O - ΔHf_CH₄ ------(3)
Sum of equations (1) and (2) gives equation (3)
So ΔH₂ = (518kJ) + (-890kJ) = -372kJ