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Which of the following are conjugate acid-base pairs ?
Which of the following are conjugate acid-base pairs ?
a) H3O+ and H2O
b) HCN and CN -
c) HIO4 and IO4-
d) KOH and OH -
e) NH4+ and NH3
6 Answers
- 1 decade agoFavorite Answer
conjugate acid-base pairs means there is a difference of ONE hydrogen atoms between the two pairs. From th elook of it, A,B,C,E
- Anonymous5 years ago
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- Anonymous1 decade ago
all of them are.
read on bronsted lowry acid base theory.
--
at short:
The Arrhenius definition of an acid and a base:
Acids - substances that when dissolved in water release H+ ions
Bases - substances that when dissolved in water release OH- ions
The definition of an Arrhenius acid and base emphasizes the H+ and OH- ions in water
J.N. BrØnsted and T.M. Lowry proposed the following definition of acids and bases in 1923: an acid is a proton donor and base is a proton acceptor . In the general reaction,
B- + HA = HB + A-
B- is base (1)
HA is acid (1)
HB is acid (2)
A- is base (2)
a proton (H+) is transferred from HA to the anion, B-. HA is considered an acid because it can donate a proton while B- is a base as it can accept a proton. Because the reaction is reversible, HB and A- form a new acid and base, respectively. The HA / A- and the HB / B- combinations which differ by only a proton are called conjugate acid-base pairs.
H3O+ and H2O
H2O + H2O = H3O+ + OH-
H2O : acid(1)
H2O : base(1)
H3O+ is acid(2) conjugate to base (1)
OH- is base(2) conjugate to acid(1)
so H3O+ and H2O are conjugate acid-base pairs.
What enables water to act as either an acid or base is its ability to reversibly ionize as depicted in the reaction H2O + H2O = H3O+ + OH-
HCN and CN -
HCN + H2O = H3O+ + CN-
HCN is acid (1) giving a proton to become CN- (base)
H2O is base(1)
H3O+ is acid (2)
CN- is conjugate base from HCN
so, HCN and CN - are conjugate acid-base pairs.
HIO4 and IO4-
HIO4 + H2O = H3O+ + IO4-
HIO4 is acid (1) giving a proton to become IO4- (base)
H2O is base(1)
H3O+ is acid (2)
IO4- conjugate base from HIO4
so, HIO4 and IO4- are conjugate acid-base pairs.
KOH and OH -
KOH + H2O = KH2O+ + OH-
KOH base(1)
H2O acid(1)
KH2O+ acid(2)
OH- base(2)
KOH and OH - are conjugate acid-base pairs.
i am not sure about KOH + H2O = KH2O+ + OH- but i know KOH is a strong base.
(check other literature please)
NH4+ and NH3
NH4+ + OH- = NH3 + H2O
NH4+ is acid(1)
OH- is base(1)
NH3 is base(2)
H2O is acid(2)
NH4+ and NH3 are conjugate acid-base pairs.
- Anonymous7 years ago
challenging thing. look with google. it will help!
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