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Equilibrium...?

You place 3.00 mol of pure SO3 in an 8.00 L flask at 1150 K. At equilibrium, 0.58 mol of O2 has been formed. Calculate K for the reaction at 1150 K.

2SO3(g) ↔ 2SO2(g) + O2(g)

show work plz.

2 Answers

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  • Dr.A
    Lv 7
    1 decade ago
    Favorite Answer

    Initial concentration SO3 = 3.00 mol / 8.00L = 0.375 M

    Concentration O2 at equlibrium = 0.58 mol / 8.00 = 0.0725 M

    2 SO3 <-----> 2SO2 + O2

    initial concentration

    0.375

    change

    -2x. . . . . . . . .. +2x. . . .+x

    at equilibrium

    0.375-2x . . . .. . 2x. . . . .. x

    x = 0.0725

    2x = 0.145

    concentration SO3 = 0.375 - 0.145 = 0.230 M

    K = (0.145)^2 ( 0.0725) / (0.230)^2 = 0.0288

  • 1 decade ago

    The equilibrium constant is computed from the equilibrium concentrations.

    Start with the balanced chemical equation

    2SO3(g) <==> 2SO2(g) + O2(g)

    Compute the equilibrium concentrations of the reactants and products.

    [SO3] = 2.42 mol / 8 L = 0.3025 mol / L

    [SO2] = 0.58 mol / 8 L = 0.0725 mol / L

    [O2] = 0.29 mol / 8 L = 0.03625 mol/L

    Plug the equilibrium concentrations into the equation, and don't forget to square the ones that need it.

    Keq = [SO2]^2 [O2] / [SO3]^2

    Keq = 0.00208

    Source(s): 35 years of teaching chemistry
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