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Why do carboxylic acids generally have higher melting and boiling points than alcohols, ketones, and aldehydes?

Why do carboxylic acids generally have higher melting and boiling points than alcohols, ketones, and aldehydes of comparable mass?

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  • 1 decade ago
    Favorite Answer

    carboxylic acids with the presence of -COOH groups are capable of hydrogen bonding between molecules and more energy is necessary to overcome this additional intermolecular bonding, hence, the melting and boiling points for carboxylic acids are generally higher.

  • 5 years ago

    1

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  • ?
    Lv 4
    4 years ago

    Carboxylic Acid Melting Point

  • 6 years ago

    This Site Might Help You.

    RE:

    Why do carboxylic acids generally have higher melting and boiling points than alcohols, ketones, and aldehydes?

    Why do carboxylic acids generally have higher melting and boiling points than alcohols, ketones, and aldehydes of comparable mass?

    Source(s): carboxylic acids generally higher melting boiling points alcohols ketones aldehydes: https://shortly.im/Qf05o
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  • Anonymous
    5 years ago

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    The acid group is stabilized through resonance. The double bond can lie on either of the oxygens, and that stabilizes the molecule. More stable molecules have higher boiling points (and melting points). Alcohols, ketones, and aldehydes to not have resonance to stabilize them, so their boiling points are much lower.

  • 1 decade ago

    this is so because the above mentioned carboxylic acids have stronger bonds/ van der walls forces between them thus it takes a much higher amount of heat to break the forces thus the higher melting and boiling points

  • 5 years ago

    because more energy is require to break the o-h bonds in carboxylic acids

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