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Does any substance other than water sublime?

An ice cube escaping my G&T landed on a piping hot griddle and immediately started to simultaneously melt and sublime.

And it made me wonder, are there any other substances that sublime? I have to admit that I cannot remember that piece of information that I was undoubtedly told at school!

Update:

dry ice is liquid nitrogen which is then turning into a gas.

Therefore it is not subliming, as this term means to turn from solid to gas without going through a liquid stage.

I was wondering if I would get this as an answer!

Update 2:

Thank you for the correction, I have long been mistaken.

However Dr Jay could learn a little courtesy, I'm assuming she is very young.

My lack of chemical knowledge is the basis as to why I posed the question. Luckily I'm not bothered about being wrong, nor am I easily cowed. I like to learn and one can only learn by listening to explanations.

People who use this forum to put other down (most probably as a means of feeling better about themselves) may have some specific knowledge but aren't particularly bright.

Have a nice day! :)

8 Answers

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  • 1 decade ago
    Favorite Answer

    Dry ice (solid carbon dioxide) is an example of a substance which sublimes at room temperature and pressure. Presumably that is how it got its name as there is no wetness when it transforms. Dry ice sublimes because the most thermodynamically favourable transition under these conditions is directly from solid to gas (with no intermediate liquid phase).

    The state which a substance takes is determined by thermodynamics. All substances have what is called a triple point. This is the unique temperature and pressure at which all three phases, solid, liquid and gas can exist simultaneously.

    Since most experiments are conducted at atmospheric pressure there is limited opportunity to observe sublimation. However, if we can adjust the pressure we can observe sublimation for any substance.

  • 1 decade ago

    Dry ice is actually solid carbon dioxide (CO2), which does sublime (liquid nitrogen is N2). All solids sublime to a certain degree, even gold bars! The reason you don't notice most of the time is because the rate of sublimation is so slow that it would take many lifetimes for a noticeable change in size.

    To make sublimation make more sense, think of it as a solid dissolving in a gas. If you have air around a chunk of ice but the air is colder than 0ºC, the ice will not melt. But if the air is very dry it will dissolve some of the water molecules without those molecules ever entering the liquid phase. Proof it works: can you smell a solid wax candle? What you're smelling is molecules of that candle that are dissolved in air.

  • 1 decade ago

    OK Let us cut out all the mutual bad mouthing and return to science,

    1) we have concluded quite correctly that water does not sublime

    2) we have also concluded correctly that dry ice is solid carbon dioxide that does sublime

    3) what other common substance sublimes? We are forgettong the most obvious and simplest one - pure iodine: To quote from Wiki:

    Iodine under standard conditions is a shiny grey solid. It can be seen subliming at standard temperatures into a violet-pink gas that has an irritating odor.

    4) can anybody else make a courteous contribution to this discusssion?

  • Anonymous
    1 decade ago

    The organic substance called ferrocene sublimes nicley, a good way to purify as only the ferrocene goes into gas phase when heated leaving impurities behind, you can recondense the pure substances in a filter funnel over a hotplate.

    *******Dry ice is solid CO2 not liquid nitrogen!!. (1)

    Source(s): (1) Chemistry and Chemical Reactivity (fourth edition), Kotz and Treichal page 632
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  • 1 decade ago

    Two things - firstly, water does NOT sublime at atmospheric pressure, you are mistaken. You said it melted and sublimed simultaneously, and that is not so.

    Secondly, dry ice is NOT liquid nitrogen. It's SOLID carbon dioxide, whose sublimation gives the cloudy gas effect.

    Your really need to brush up on your basics.

  • 1 decade ago

    Iodine

    Ferrocene (FeC10H10) sublimes at about 84 degrees C

    Nickelocene (NiC10H10)

    Gallium trifluoride (GaF3)

    Uranium hexafluoride (UF6)

    Mercurous fluoride (HgF)

    Mercurous chloride (HgCl)

    Mercurous bromide (HgBr)

    Source(s): MChem lecture notes
  • 1 decade ago

    dry ice...makes fog

  • 1 decade ago

    napthalene balls....camphor.....Copper sulphate crystals...etc....run a google search!

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