On Chuck Vs the Cubic Z what is the name of the song that is keeps playing though out the episode?

This week in "Chuck" music: "Beat the Devil's Tattoo" by Black Rebel Motorcycle Club (a recurring theme involving the two prisoners), "Don't Shoot (I'm a Dead Man" by DEVO (Chuck, Sarah and Heather are trapped in the cell while Hugo goes to work in Castle), "Land of the Freak" by King Khan & the Shrines (the Buy More riot) and "In the Valley" by Chief (Morgan gives Big Mike his blessing, and the ring falls down into Castle).

Assuming you have done the required steps of connecting the iPod to a computer with iTunes, putting music onto it and charging it, all you have to do is plug in some earphones, turn the device on and press 'play'.