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Chem 2: Vapor Pressure, Boiling Point & Intermolecular forces?
I have been trying to figure out this question for quite some time now,
If possible i'd like an explanation to the answer as well.
Thanks for your time and help!
At 187°C the vapor pressure of antimony trichloride is 0.5 atm.
At 249°C the vapor pressure of antimony tribromide is 0.5 atm.
Predict the answers to all of the following questions by selecting the correct molecular substance in each case.
Which substance exhibits weaker attractive intermolecular forces?
SbCl3
SbBr3
Which substance has the lower normal boiling point?
SbBr3
SbCl3
Which substance will evaporate more slowly at 210°C?
SbCl3
SbBr3
Which substance has the lower vapor pressure at 180°C?
SbBr3
SbCl3
My Answers:
SbCl3
SbCl3
SbCl3
SbBr3
Not sure what else there is to say...
I presume that because the SbCl3 achieves .5 atm at a lower temperature it has weaker Intermolecular forces, which allow it to be be boiled at a lower temperature.
I presume that because at 210 SbCl3 is already at equilibrium (I think?) it will also evaporate slowers.
Because it takes 249 degrees to get the SbBr3 to .5 atm, I also presume that it would have the lower vapor pressure at 180 degrees.
All that in mind, I've been wrong time and time again.
All help is appreciated!
3 Answers
- Anonymous1 decade agoFavorite Answer
At 187°C the vapor pressure of antimony trichloride is 0.5 atm.
At 249°C the vapor pressure of antimony tribromide is 0.5 atm.
Predict the answers to all of the following questions by selecting the correct molecular substance in each case.
Which substance exhibits weaker attractive intermolecular forces?
***SbCl3 ...weaker because it acheives the same vapor pressure at a lower temp
SbBr3
Which substance has the lower normal boiling point?
SbBr3
**SbCl3 its got a head start at 0.5 atm
Which substance will evaporate more slowly at 210°C?
SbCl3
SbBr3 .....this one its vapor pressure <0.5 but choride >0.5
Which substance has the lower vapor pressure at 180°C?
SbBr3 ...this one it will come down way less than 0.5 atm
SbCl3
My Answers:
SbCl3
SbCl3
SbCl3...think wrong At 187°C the vapor pressure of antimony trichloride is 0.5 atm.
At 249°C the vapor pressure of antimony tribromide is 0.5 atm. think about it at 180C choride vapor pressure will be slighlty less than 0.5 atm BUT bromine will drop like a rock becaue you are now 100C less than the vapro pressure at 0.5 atm
SbBr3
Source(s): Soc - kerstenLv 44 years ago
A. A low warmth of vaporization shows that this is incredibly straight forward to transform a liquid to a gas. If this is real, the intermolecular forces between the liquid atoms could desire to be susceptible.
- Anonymous1 decade ago
Ok... while I think I get what you are meaning, we can offer you a more thorough answer if you write more information. Just add more and I will come back! ;p
Source(s): Anyways best wishes!