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Chem 2: Vapor Pressure, Boiling Point & Intermolecular forces?

I have been trying to figure out this question for quite some time now,

If possible i'd like an explanation to the answer as well.

Thanks for your time and help!

At 187°C the vapor pressure of antimony trichloride is 0.5 atm.

At 249°C the vapor pressure of antimony tribromide is 0.5 atm.

Predict the answers to all of the following questions by selecting the correct molecular substance in each case.

Which substance exhibits weaker attractive intermolecular forces?

SbCl3

SbBr3

Which substance has the lower normal boiling point?

SbBr3

SbCl3

Which substance will evaporate more slowly at 210°C?

SbCl3

SbBr3

Which substance has the lower vapor pressure at 180°C?

SbBr3

SbCl3

My Answers:

SbCl3

SbCl3

SbCl3

SbBr3

Update:

Not sure what else there is to say...

I presume that because the SbCl3 achieves .5 atm at a lower temperature it has weaker Intermolecular forces, which allow it to be be boiled at a lower temperature.

I presume that because at 210 SbCl3 is already at equilibrium (I think?) it will also evaporate slowers.

Because it takes 249 degrees to get the SbBr3 to .5 atm, I also presume that it would have the lower vapor pressure at 180 degrees.

All that in mind, I've been wrong time and time again.

All help is appreciated!

3 Answers

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  • Anonymous
    1 decade ago
    Favorite Answer

    At 187°C the vapor pressure of antimony trichloride is 0.5 atm.

    At 249°C the vapor pressure of antimony tribromide is 0.5 atm.

    Predict the answers to all of the following questions by selecting the correct molecular substance in each case.

    Which substance exhibits weaker attractive intermolecular forces?

    ***SbCl3 ...weaker because it acheives the same vapor pressure at a lower temp

    SbBr3

    Which substance has the lower normal boiling point?

    SbBr3

    **SbCl3 its got a head start at 0.5 atm

    Which substance will evaporate more slowly at 210°C?

    SbCl3

    SbBr3 .....this one its vapor pressure <0.5 but choride >0.5

    Which substance has the lower vapor pressure at 180°C?

    SbBr3 ...this one it will come down way less than 0.5 atm

    SbCl3

    My Answers:

    SbCl3

    SbCl3

    SbCl3...think wrong At 187°C the vapor pressure of antimony trichloride is 0.5 atm.

    At 249°C the vapor pressure of antimony tribromide is 0.5 atm. think about it at 180C choride vapor pressure will be slighlty less than 0.5 atm BUT bromine will drop like a rock becaue you are now 100C less than the vapro pressure at 0.5 atm

    SbBr3

    Source(s): Soc
  • 4 years ago

    A. A low warmth of vaporization shows that this is incredibly straight forward to transform a liquid to a gas. If this is real, the intermolecular forces between the liquid atoms could desire to be susceptible.

  • Anonymous
    1 decade ago

    Ok... while I think I get what you are meaning, we can offer you a more thorough answer if you write more information. Just add more and I will come back! ;p

    Source(s): Anyways best wishes!
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