does the number of electron have anything to do with change in temperature of an element? What law is this?

in semiconductors the number of electrons in th econduction band is a function of temperature and is governed by Fermi-Dirac statistics.

In elements at super hot tempertures the electrons can be ionized away.

I would call it Boltzman's law in this case

No, it shouldn't, unless there is some critical piece of information you've left out.

Temperature is a measure of average kinetic energy in a system, as such the number of electrons present should have anything to do with temperature unless you introduce electrons in such a way that they add to the total kinetic energy of the system.

Is there more to the question that you have omitted? I am not familiar with any law or equations relation quantity of electrons to temperature.

the form of electrons are a similar form of protons. the atomic form of the component identifies the form of protons. the form of neutrons is discovered by using rounding the atomic mass to the closest total type and subtract that from the atomic type.