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Balancing Redox Equation...Help!?
H2O2 + Mn^2+ --> MnO4^- + H^+ + H2O
Mn^2+ --> MnO4^- (+2 --> +7) = Oxidation
Half equation:
Mn^2+ --> MnO4^- + 5e-
I've problem with the reduction half-equation for this problem...Help!
2 Answers
- HalchemistLv 79 years agoFavorite Answer
Mn^2+ --> MnO4^- + 5e- ( now balance charge with water and H+
4 H2O + Mn^2+ ----------> MnO4^- + 5 e- + 8H+ (use 4 H2O on left to provide O for MnO4-)
H2O2 + 2 H+ + 2 e- --------> 2 H2O (least common multiple 2,5 is 10 so cross multiply to balance electrons, tyhen cancel like terms.
2 Mn^2+ + 5 H2O2 + 10 H+ + 8H2O ----> 2 MnO4^- + 10 H2O + 16 H+
2 Mn^2+ + 5 H2O2 -------> 6 H+ + 2 MnO4^- + 2 H2O (balanced atoms and charge)
- hcbiochemLv 79 years ago
Start with the two half-reactions and make sure the atoms that are changing oxidation state are balanced:
Mn2+ --> MnO4-
H2O2 --> 2 H2O
Next, balance oxygens by adding H2O
Mn2+ + 4 H2O --> MnO4-
H2O2 --> 2 H2O
Now, balance hydrogen by adding H+:
Mn2+ + 4 H2O --> MnO4- + 8 H+
2 H+ + H2O2 --> 2 H2O
Now, balance charges by adding e-:
Mn2+ + 4 H2O --> MnO4- + 8 H+ + 5 e-
2 H+ + 2 e- + H2O2 --> 2 H2O
Now, you multiply one or both equations by a small number to make the number of electrons the same in the two reactions:
2 Mn2+ + 8 H2O --> 2 MnO4- + 16 H+ + 10 e-
10 H+ + 10 e- + 5 H2O2 --> 10 H2O
Now, add the two equations, cancelling anything that is on both sides:
2 Mn2+ + 5 H2O2 --> 2 MnO4- + 2 H2O + 6 H+
And you're done...