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Balancing Redox Equation...Help!?

H2O2 + Mn^2+ --> MnO4^- + H^+ + H2O

Mn^2+ --> MnO4^- (+2 --> +7) = Oxidation

Half equation:

Mn^2+ --> MnO4^- + 5e-

I've problem with the reduction half-equation for this problem...Help!

2 Answers

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  • 9 years ago
    Favorite Answer

    Mn^2+ --> MnO4^- + 5e- ( now balance charge with water and H+

    4 H2O + Mn^2+ ----------> MnO4^- + 5 e- + 8H+ (use 4 H2O on left to provide O for MnO4-)

    H2O2 + 2 H+ + 2 e- --------> 2 H2O (least common multiple 2,5 is 10 so cross multiply to balance electrons, tyhen cancel like terms.

    2 Mn^2+ + 5 H2O2 + 10 H+ + 8H2O ----> 2 MnO4^- + 10 H2O + 16 H+

    2 Mn^2+ + 5 H2O2 -------> 6 H+ + 2 MnO4^- + 2 H2O (balanced atoms and charge)

  • 9 years ago

    Start with the two half-reactions and make sure the atoms that are changing oxidation state are balanced:

    Mn2+ --> MnO4-

    H2O2 --> 2 H2O

    Next, balance oxygens by adding H2O

    Mn2+ + 4 H2O --> MnO4-

    H2O2 --> 2 H2O

    Now, balance hydrogen by adding H+:

    Mn2+ + 4 H2O --> MnO4- + 8 H+

    2 H+ + H2O2 --> 2 H2O

    Now, balance charges by adding e-:

    Mn2+ + 4 H2O --> MnO4- + 8 H+ + 5 e-

    2 H+ + 2 e- + H2O2 --> 2 H2O

    Now, you multiply one or both equations by a small number to make the number of electrons the same in the two reactions:

    2 Mn2+ + 8 H2O --> 2 MnO4- + 16 H+ + 10 e-

    10 H+ + 10 e- + 5 H2O2 --> 10 H2O

    Now, add the two equations, cancelling anything that is on both sides:

    2 Mn2+ + 5 H2O2 --> 2 MnO4- + 2 H2O + 6 H+

    And you're done...

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