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What is the volume of oxygen? ** 10pts?

For the electrolysis described below:

what volume of pure oxygen gas is evolved at 16°C and 768 Torr for every kilogram of gold produced??

4Au(CN)4- + 12OH- 4Au + 16CN- + 3O2 + 6H2O

My attempt: (.00375*.0821*289.15)/1.01 ATM

= .08809 L but that is incorrect. Please explain.

2 Answers

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  • 9 years ago
    Favorite Answer

    From your equation I interpret that:

    When 4 mol Au produced , then 3 mol O2 produced.

    Molar mass Au = 196.97g/mol

    1000g = 1000/196.97 = 5.08 mol Au produced

    This will result in 5.08*3/4 = 3.81 mol O2 being produced.

    Calculate volume using ideal gas equation:

    PV = nRT

    P = pressure = 768 torr = 1.0105 atm

    V = What you want

    n = mol = 3.81

    R =- constant = 0.082057

    T = temp = 16°C = 289K

    Substitute

    1.0105 * V = 3.81*0.082057*289

    V = 90.352 / 1.0105

    V = 89.4L

    Volume of O2 produced = 89.4L

  • 4 years ago

    Volume Of Oxygen

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