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Making a buffer solution?

this is a test question i had, for some reason i got really lost on it, and i wanted to know the answer incase it shows up in the future.

use the henderson0 hasselbach equation to perform the following calculation. (The Ka of acetic acid is 1.8* 10^-5).

Calculate the mass of solid sodium acetate required to mix with 100 ml of 0.1 M acetic acid to prepare a pH 4 buffer.

i get a little confused with the equation, because i dont know which conj base and acid concentration to use for th henderson-hasselbach equation.

any help would be appreciated, thank you.

Update:

after posting, i tried it again, and i got 4.557 g. now i think i did it right. if anyone could clarify, or show they got the same would be awesome

Update 2:

omg, thank you so much, i had the conj base and acid flipped around, you answered my main question in the first 3 sentances

Update 3:

omg, thank you so much, i had the conj base and acid flipped around, you answered my main question in the first 3 sentances

1 Answer

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  • 8 years ago
    Favorite Answer

    The HH equation states pH = pKa + log [salt]/[acid] or + log [conj base]/[acid]

    For acetic acid/acetate buffer, obviously the acetic acid is the acid, and the acetate is the conj base

    So for pH 4 you have 4 = 4.74 + log [acetate]/[acetic acid]

    log [acetate]/[acetic acid] = 4 - 4.74 = -0.74

    log acetate - log 0.1 = -0.74

    log acetate = -0.74 + log 0.1

    log acetate = -1.74

    acetate = 0.018 M

    molar mass of sodium acetate = 82 g/mole

    0.018 mol/L x 0.1 L = 0.0018 moles

    0.0018 moles x 82 g/mol = 0.1476 grams

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