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? asked in Science & MathematicsChemistry · 8 years ago

Chemistry chemistry concerning moles?

I got this question wrong on an exam and I need clarification as to why I got it wrong.

A student spilled 100.0 ml of 6.00M HCL (aq) on the work bench and tried to neutralize it with 0.125 L of 4.00M NaHCO3 (aq).

Will that be enough to get rid of all the acid? Why or why not?

As for my calculations, I did (6M HCL/100 mL) * (1000 mL/1 L) to find the molarity of HCL.

I did (4M NaHCO3/.125 L) * 1 L to find the molarity of NaHCO3.

In the end, my explanation was that even though the student is using more volume to clean up the HCL spill, it contains a smaller molarity than the 100 mL of 6.00 M HCL, so it would not be enough to get rid of the acid.

Any answer is appreciated.

1 Answer

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  • 8 years ago
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    moles of HCl = 0.1 L x 6 mol/L = 0.6 moles HCl

    moles NaHCO3 = 0.125 L x 4 mol/L = 0.5 moles NaHCO3

    According to the balanced equation of HCl + NaHCO3 --> NaCl + CO2 + H2O it takes 1 moles NaHCO3 to neutralize 1 moles HCl. You don't have enough NaHCO3 (0.5 moles) to neutralize all HCl (0.6 moles).

    NOTE: It is the number of MOLES and not the MOLARITY that matters. In your answer, you use the term molarity, which is incorrect.

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