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Can someone explain how this metal complex is formed?

CoCl2 + water = [Co(H20)6]^2+ + 2Cl^-

From what I understand Co in this reaction has a charge of +2 since it has bonded with 2 Cl ions which have a -1 charge. Then we have an empty 4s orbital, 7 electrons in the 3d orbital and an empty 4p orbital. This gives us a total of 11 electrons that can occupy these orbitals and so a maximum of 5 electron pairs right? But according to the equation 6 electron pairs have been formed. How is this possible?

I'm confused so if anyone who knows where I am going wrong or what I have misunderstood please let me know.

Thanks

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  • 8 years ago
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    The nature of the bonding between ligands (H2O) and transition metal ions (Co2+), as in this case, cannot be viewed as pure dative covalent, but rather is partial donation of ligand electron pairs and partial electrostatic attraction. There simply enough gaps for all the ligand lone pairs, as you suspect.

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