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? asked in Science & MathematicsChemistry · 4 years ago

Molecular formula question?

If 4.04 g of Nitrogen combines with 11.46 g of Oxygen to produce a compound with a molar mass of 108.0 g, what is the molecular formula of this compound?

2 Answers

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  • 4 years ago

    First, get the empirical formula:

    4.04 g / 14.0 g/mol = 0.28857 mol

    11.46 g / 16.0 g/mol = 0.71625 mol

    Look for smallest whole-number ratio:

    0.28857 mol / 0.28857 mol = 1

    0.71625 mol / 0.28857 mol = 2.482

    The smallest whole-number ratio is 2:5.

    The empirical formula is N2O5

    What is the weight of N2O5?

    (14 x 2) + (16 x 5) = 108

    108 / 108 = 1

    N2O5 is also the molecular formula.

    =============================================

    Suppose the molecular weight was 216. We then have this:

    216 / 108 = 2

    N2O5 times 2 = N4O10 <--- that's the molec formula for my additional example

  • 4 years ago

    moles N = 4.04 g x 1 mol/14 g = 0.2886 moles

    moles O = 11.46 g x 1 mol/16 g = 0.716 moles

    Dividing by 0.2886 to get whole numbers, you have 1 N and 2.5

    Then multiply by 2 to get 2N and 5O, so empirical is N2O5

    Molec. wt of empirical is 14+14+ (5x16) = 28 + 90 = 108

    So, molecular formula is N2O5

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