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Combustion of 25.0 g of a hydrocarbon produces 86.5 g of CO2. What is the empirical formula of the compound?

I don't understand how to do combustion problems if water isn't given. How do I do this?

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  • 4 years ago
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    Since it is a hydrocarbon you don't need to know about water. You can figure the mass of H instead.

    (86.5 g CO2) / (44.00964 g CO2/mol) × (1 mol C / 1 mol CO2) = 1.9655 mol C

    (1.9655 mol C) × (12.01078 g C/mol) = 23.6072 g C

    (25.0 g total) - (23.6072 g C) = 1.3928 g H

    (1.3928 g H) / (1.007947 g H/mol) = 1.3818 mol H

    Divide by the smaller number of moles:

    (1.9655 mol C) / 1.3818 mol = 1.4224

    (1.3818 mol H) / 1.3818 mol = 1.000

    In order to achieve integer coefficients, multiply by 7, then round to the nearest whole numbers to find the empirical formula:

    C10H7

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