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Mean Free Path: Physics Question?

Calculate the mean free path of air molecules at a pressure of 5.00×10−13 atm and a temperature of 292 K .

(This pressure is readily attainable in the laboratory.)

Model the air molecules as spheres with a radius of 2.00×10−10 m.

Any help would be greatly appreciated.

Thank you in advance

1 Answer

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  • hfshaw
    Lv 7
    3 years ago
    Favorite Answer

    The mean free path of molecules in a gas a a temperature T and pressure p is given by:

    λ = R*T/[sqrt(2)*π*d²*N*p]

    where R is the universal gas constant, d is the effective diameter of the molecules, and N is Avogadro's number. [derivation given in source]

    In this case,

    λ = (8.206*10^(-5) m³*atm/(mol*K))*(292 K)/[sqrt(2)*π*(4.00*10^(-10)m)²*(6.022*10^23/mol)*(5.00*10^(-13) atm)]

    λ = 1.12*10^5 meters = 112 km = 69.6 mi (to the appropriate number of significant figures)

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