Can I go into a car showroom and offer them an Avon book?

No law against it.

If you want.  You might not get the response you want though

Probably. Just make sure there are no drugs or pornography in it and you'll be okay.  Thats said, in some car showrooms you may stand a better chance if you do have drugs and porn.  

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Yes you can!!! Some business have no soliciting signs posted and those places wouldn't be that accepting of your interruption.

As long as it doesn’t interfere with their business it fair game. Create a win-win if you can.  If thee manager is a dick naysayer then just put a bunch on the windshields of all the used cars on the way off the lot.  Door to door can be tough, but you can’t have “no” in your heart forever.

Sure but don't expect a free car.

You can. You might not get a particularly positive reception.

You can do - they can offer you a car brochure in return