I want to buy a men's pullover hoody. I usually wear a large in women's shirts. What size should I order?

For a mans size, i would either go one size down to a medium or try the large in the mens, because i see that you are concerned about your chest area. mens shirts arent made to fit a womans chest, so a large in a mens may work for you.

I'd say you should still go with the Large in a mans size too. Like you said, you have a D chest size so you'll probably be more comfy in the extra room that that large in mens size gives you. I'm not sure how women measure their sizes, but a man measures his by the chest size. 42 - 44 is usually a large, and given that you'll probably want/need to extra space in the top area then a Large will probably be what you need. Also, don't forget that most "hoodies" are made form 100% cotton so they will shrink some.

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medium