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how do you find the amount of Joules gained by a calorimeter (gen chem help)?

Given

HNO3 + KOH --> KNO3 (aq he) + H20

the heat gained by the calorimeter and the heat of the reaction (assume the density and the specific heat are the same as distilled water):

Temp of 50.0 mL of HNO3 before mixing : 22.0 degrees Celsius

Temp of 50.0 mL of KOH before mixing : 22.0 degrees Celsius

Temp of 100.0 mL of reaction mixture : 34.5 degrees Celsius

how many joules are gained my the solution, how many joules are gained by the calorimeter and what is the heat of reaction?

1 Answer

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  • ?
    Lv 7
    10 years ago
    Favorite Answer

    50ml HNO3 = 50g

    50ml KOH = 50g

    100g x 4.184J/g-ºC x 12.5ºC = 5230J = heat gained by the solutions

    5230J = heat of reaction

    both the calorimeter and the liquids have the same temperature throughout the reaction so they have the same deltaT

    Q = heat rxn + heat cal

    Qtcal = Ccal x deltaT

    Qwater = Cwater x deltaT

    both the water and calorimeter have the same temperature

    so, since they share the same deltaT

    C system = C water + C cal

    heat absorbed by solution = 4.184J/ºC x 12.5ºC = 52.3J

    so, the rest of it has to be the heat absorbed by the calorimeter = 5230 - 52.3 = 5177.7J

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