Yahoo Answers is shutting down on May 4th, 2021 (Eastern Time) and beginning April 20th, 2021 (Eastern Time) the Yahoo Answers website will be in read-only mode. There will be no changes to other Yahoo properties or services, or your Yahoo account. You can find more information about the Yahoo Answers shutdown and how to download your data on this help page.

? asked in Science & MathematicsChemistry · 10 years ago

iit jee chemistry can anyone explain to me in simple terms what are kjeldal and lassaigne's test for nitrogen?

i also need to know in what cases they fail .Waiting urgently for response....

1 Answer

Relevance
  • 10 years ago
    Favorite Answer

    kjeldal method

    i am explaining the method in short diagram part u can look for ur self

    the compd containing N( nitrogen ) is heated with sulphuric acid , to get convetrted into ammonium sulphate which is then distilled with sodium hydroxide solution to form ammonia , the evolved ammonia is made to pass into excess of known amt of standard acid solution , the amount of ammonia formed in the above reaction reacts with equivalent amount of standard acid , and then the excess acid left is estimated by titrating against standard alkali solution . this is back titration and from this reading the amount of nitrogen in the given organic compound can be estimated.

    the rreactions are

    C+H+S gives in presence of H2SO4 CO2+H2O+SO2

    N in presence of H2SO4 gives (NH4)2SO4

    lassaigne's test for nitrogen

    the organic compound is first convertedinto soluble extract form . the organic compound containing N is fused with sodium metal and plunged into dis water , the contents are then boiled to form its sodium extract or lassaigne's extract to this extract small amount of ferrous sulphate solution is added warmed a few drops of ferric chloride is then added and the resulting solution is acidified with dil HCl . the appearance of prussian blue color shows the presence of N

    the reactions

    Na+C+N --NaCN

    FeSO4+2NaCN ----Fe(CN)2 +NaSo4

    Fe(CN)2+4NaCN ------Na4[Fe(CN)6] sodium ferrocynadie

    3Na4[Fe(CN)6]+6FeCl3-Fe4[Fe(CN)6]3 +12NaCl

Still have questions? Get your answers by asking now.