Yahoo Answers is shutting down on May 4th, 2021 (Eastern Time) and beginning April 20th, 2021 (Eastern Time) the Yahoo Answers website will be in read-only mode. There will be no changes to other Yahoo properties or services, or your Yahoo account. You can find more information about the Yahoo Answers shutdown and how to download your data on this help page.

How can something be an acid if it doesn't have a hydrogen to donate?

So for instance, why does NiCl_2_ form an acid?

2 Answers

Relevance
  • 9 years ago
    Favorite Answer

    The Ni^2+ ion is an electron-deficient species. Under Lewis acid base theory, it is an acid. Other Lewis acids include Al^3+ (as AlCl3 usually), Fe^3+ (usually as Fe(NO3)3). BF3 is another Lewis acid.

    Lewis bases are electron-rich species. Examples include NH3 and H2O. Interestingly, double bonds (being an electron-rich area) can function in a Lewis base way in certain reactions.

    Source(s): ChemTeam
  • 9 years ago

    You must make it clear what type of acid you are referring to:

    Brønsted acids are H^+ donors; Lewis acids are e⁻ pair acceptors.

    NiCl2 as a Brønsted acid:

    NiCl2(s) + ∞H2O → [Ni(H2O)6]^2+ + 2Cl^-(aq)

    [Ni(H2O)6]^2+ + H2O ⇋ [Ni(H2O)5(OH)]^+ + H3O^+ pKa = ~10 a weak Brønsted acid.

    As a Lewis acid: H2O:→Ni^2+ as in [Ni(H2O)6]^2+; H3N::→Ni^2+ as in [Ni(NH3)6]^2+

    Cl:→Ni^2+ as in [NiCl4]^2-

Still have questions? Get your answers by asking now.