Using Graphics Tablet as a stand-alone monitor, while PC Monitor is also on its own?

I recently got a Yiynova MVP10U and I'm in love with it so far. But the only thing that keeps confusing me, and makes it difficult to draw is the monitor settings on Windows 8.1. I've tried several different combinations so that I can just use the Yiynova to draw, and have my PC monitor just show my desktop. This gets very confusing especially when I start streaming. I'll capture the 2nd monitor (Yiynova), but my mouse would wander onto my main display (PC Monitor). Is there anyway for the Yiynova to be able to display my art programs, and the PC monitor be for displaying my desktop background?

I want to be able to have Photoshop and Paint Tool Sai on my Yiynova screen, and the stream's chat on my PC Monitor.

Thanks!