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Me asked in Science & MathematicsChemistry · 5 years ago

Colligative property question?

How's the relation i = 1 + alpha deduced

For the question- pH of a 0.1M monobasic acid is found to be 2.Hence its osmotic pressure at a given temp T is the solution is:

[H+]=C*alpha

Therefore alpha=0.01/0.1=0.1

Now,

i=alpha +1

i=0.1+1

i=1.1

Osmotic pressure

=CRTi

=0.1RT1.1

=0.11RT

So here what does i = alpha + 1 stand for? Any formula or ideas to deduce this or perhaps another way by which the question can be solved

1 Answer

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  • Fern
    Lv 7
    5 years ago
    Favorite Answer

    The dissociation degree is the fraction of original solute molecules that have dissociated. It is usually indicated by the Greek symbol α. More accurately, degree of dissociation refers to the amount of solute dissociated into ions or radicals per mole. In case of very strong acids and bases, degree of dissociation will be close to 1. Less powerful acids and bases will have lesser degree of dissociation. There is a simple relationship between this parameter and the van 't Hoff factor i

    Source: https://en.wikipedia.org/wiki/Dissociation_%28chem...

    pH = 2 ; [H+] = 0.01

    [HA] = 0.10

    Degree of Dissociation; alpha = 0.01/0.10 = 0.10

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