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Mastering Chem Partial Pressure Q?

Assignment 1 Exercise 20.9

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Exercise 20.9

In the reaction A(g)→2B(g)+C(g),

the total pressure increases while the partial pressure of A(g) decreases. The initial pressure of A(g) in a vessel of constant volume is 6.600×10^3 mmHg .

Thru ICE diagram I found the total pressure after the reaction as gone to competion is Pt= 1.980x 10^-4 mmHg.

However what will be the total gas pressure when the partial pressure of A(g) drops to 7.60x10^-2 mmHg?

Pt= ?

How would I go about this???

1 Answer

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  • 4 years ago

    (6.600 × 10^3 mmHg) - (7.60x10^-2 mmHg) = 6599.924 mmHg A reacted

    (6599.924 mmHg A) x (3 mol products / 1 mol reactant) = 19799.772 mmHg products

    (19799.772 mmHg products) + (7.60 x 10^-2 mmHg) = 19799.848 mmHg total

    But when you round off correctly the answer is the same as if all the A had been consumed.

    This is not surprising since all of "7.60x10^-2 mmHg" is outside the significant-digit limit of "6.600×10^3 mmHg" in the first place.

    Supposing all the given number have been copied correctly, your answer for the total volume ought to be

    1.980 x 10^+4 mmHg.

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