What are the best exercises for a person who carries alot of upper body weight? (apple shape)?

Start doing incline presses 1st during your workout. This will work your upper chest before its tired. Go high weight low reps to speed up muscle growth. Then work the middle of your chest. In 2 months you will see a huge improvement

1) incline presses 5sets 8, 6, 4, 2, 1

2) Flyes incline 5sets 8, 6, 4, 2, 1

3) flat flyes 5sets 8, 6, 4, 2, 1

4) flat bench 5sets 12, 10, 8, 6, 4

5) push ups till exhaustion 5 sets