Romantic moments between Misty and Ash?

Ok here comes a large load of info. Get Ready!!

Ash Catches a Pokémon

Ash, willing to continue his journey alone, is followed by Misty. Upon noticing her pursuing him in Viridian Forest, Ash puts her on the spot and asks her, "Why are you still following me?". Misty sweatdrops and unconvincingly stutters back, "M...My bike! I'm holding you responsible for my bike!" in an insincere manner.

Why she is following him is made apparent near the end of the episode where she says, "I've never known anyone like him. He really does love Pokémon." She does so in body language befitting that of an infatuated girl. Also, in her statement, it is pretty much implied that she has some sort of interest in knowing Ash, who, at this point, is someone she barely knows. Furthermore, in this and the next episode, Misty seems very eager to make physical (if not courtly) contact with Ash.

The Water Flowers of Cerulean City

When Misty tells Daisy that she's back home because of Ash, Daisy thinks that Ash and Misty are a couple, which cause Misty to blush.

The School of Hard Knocks

In this episode, when Ash and Brock fall in love with Giselle, Misty gets mad. Some say that she was jealous because of Ash, but others say that was because of Brock.

The Tower of Terror

In the episode, when Misty thought that Ash had died, she is driven to almost tears, but is interrupted by Ash who comes back to life and wipes her nose and blushes.

Pokémon Fashion Flash

In this episode, when they see the ad for the salon, Misty grabs Ash's arm.

Poké Ball Peril

Near the end of the episode, with Brock having left Ash and Misty to travel alone, James says "I think we may have captured a pair of romantic creatures in our little cage," after which Jessie swoons and Meowth blurts out, "They're lovebirds!" The idea of Ash and Misty as a couple becomes a sub-theme throughout the subsequent Orange League Season, culminating into events in the 2nd movie. Ash and Misty deny it all.

Navel Maneuvers

Danny, the Navel Island Gym Leader, quickly picks up on the nature of Ash and Misty's relationship during one of their arguments and says, "I can see the two of you are pretty close." After Misty asks what he meant by that, he replied, "What's that saying? 'You always hurt the one you love'..."

Wherefore Art Thou, Pokémon

After the Nidoran kiss and evolve, Tracey comments about whether the battle or the kiss made them evolve. The idea of kissing embarrasses Misty and provokes Ash to ask the question, "Do people change when they get kissed?" after which Misty answers to him, "Guess we'll have to find out ourselves..." Earlier in the episode, Tracey compared the interaction between the Nidoran's trainers to the relationship between Misty and Ash (although both vehemently deny it).

Get Along, Little Pokémon!

Misty yells, "BE CAREFUL ASH!" before he goes to save the Magnemite. Misty has done this on many occasions.

Misty Meets Her Match

This entire episode alone serves as conclusive evidence that Misty not only likes Ash but possibly has developed a case of young love for him. Rudy, the Trovita Island Gym Leader, has a case of "love at first sight" with Misty after she saves his sister Mahri. After several advances from Rudy, Misty agrees to what is essentially an impromptu date with Rudy, leaving Ash and Tracey to themselves.

According to accounts of the original Japanese version, during the dance after the date, Rudy not only asked Misty to stay on the island, but to marry him. What is significant here is that Misty was actually considering his proposal, evidenced by the fact that she didn't refuse him outright. Throughout Ash's gym battle with Rudy, Misty is clearly torn between deciding which boy meant more to her, finally rooting for Ash in the end as Squirtle is hit by a Thunderbolt from Rudy's Starmie. Rudy, in shock mutters, "She wants him."

The fact that Ash started losing during this battle is probably because of his stress of Rudy liking Misty, but is then inspired by Misty's advice.

The Stun Spore Detour

Every time that Tracey and Ash need attention Misty comes to Ash first or expresses more concern for Ash.

Misty's jealous expressionThe Power of One

P2K, otherwise known as 'The Power of One', or 'Revelation Lugia' is the conclusion to everything related to Misty's love for Ash in the Orange Season. In this movie, Misty gets competition in the form of Melody, the Festival Maiden of the Legend Ceremony. Melody, upon greeting our heroes, immediately comes up to Ash and plants a kiss on his cheek, provoking a glare of jealousy from Misty. Also, after Melody's performance at the festival party, she quickly kneels in front of Ash and grabs hold of his arm, provoking Misty to gasp and growl again in subdued jealousy.

Also, upon being called Ash's girlfriend, Misty blushes uncontrollably.

Near the end, Misty openly admits to Melody that Ash is "her burden" and goes off to rescue him in Mel

Misty And Ash

Ash And Misty

Misty was always more "aware" (for lack of a better term) of Ash whenever Duplica of the House of Imita(tion) and her Ditto were around.

In one of the later movies before her initial departure from the series, Misty did admit to "caring" about Ash to one of the guest characters.

And when Misty had to go back home to oversee the Gym when all her sisters won that group trip (a flimsy excuse for her to leave if you ask me) Ash and her did get a little emotional with their goodbyes.

Ash finally even replaced the bicycle destroyed when they first met.

However neither character has never admitted loving the other to their face. Yet.

My personal favorite was Duplica's first appearance, when Misty and the viewers start to realize she might have feelings for Ash.

And unfortunately I've never heard of the Mermaid Chronicles before your question, but it does sound logical since Misty loves water based Pokemon.

When misty got jealous of a girl in the movie pokemon 2000 when the girl kisses ash in the cheek and she gets jealous and when the same girl told misty that there where gonna save misty`s boyfriend ash.

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I know a video going crazy around YouTube of them! It may be a real but deleted episode, but I really don't know. It's called "Under the Mistletoe", resulting in the two kissing! I've never actually seen it but I promise I will see it and give you more details!

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Watch the Pokemon movie The Power of One it was the second one made. She basically admits that she likes him when another girl shows affection for him and throughout the movie.

OMG there are tons!! :D

I have the links of the Ash and Misty scenes:

https://www.youtube.com/watch?v=FBwXm0vne_U

https://www.youtube.com/watch?v=F_dkD-i0a7Q

https://www.youtube.com/watch?v=q-B8dfQnbTo

https://www.youtube.com/watch?v=mO6AP1ra2_w

https://www.youtube.com/watch?v=zSsmWH0y1xE

https://www.youtube.com/watch?v=YhW-p__Is6E

https://www.youtube.com/watch?v=hC7My545Nlw

And one of my favourite examples showing the ultimate proof of their true real love is Misty's song! ^___^ If you haven't heard it, check it out, it's so beautiful ;__;

Link of Misty's song:

https://www.youtube.com/watch?v=9_6f6DWp7Nk

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